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S.L. 646.16 · Protection Of The Health And Safety (S.L. 646.16)

S.L. 646.16 Art. 14Offences. Transitional measures limit value of 10 3 μg NCO/m in relation to a period of hours and a short- exposure limit value of 20 μg NCO/m3 shall apply until 31 December 2028. number of the Part 1, Section of 8-hour above which period unless and 101,3 kPa possible dermal and of the diisocyanate

In KraftAmtlicher Text

Any person who knowingly or recklessly interferes with the process of providing a safe and healthy place of work shall be guilty of an offence. Substituted by: SCHEDULE I L.N. 164 of 2026.

LIST OF BINDING OCCUPATIONAL EXPOSURE LIMIT VALUES

Limit values EC CAS 8 hours (3) Short-term (4) Name of No No μg/ μg/ Notation agent ppm f/ml ppm f/ml 1 2 ( ) ( ) 3 3 m m 6 7 6 7 ( ) ( ) ( ) ( )

(5) (5) A

8 Skin ( ) Dermaland reference Diisocyanates respiratory 8 (measured as - - 6 - - 12 - -sensitisatio term 10 NCO ( )) n 9 ( )

(1) EC No, i.e., Einecs, ELINCS or NLP, is the official substance within the European Union, as defined in Annex VI, 1.1.1.2, to Regulation (EC) No 1272/2008.

(2) CAS No: Chemical Abstract Service Registry Number.

(3) Measured or calculated in relation to a reference period time-weighted average (TWA).

(4) Short-term exposure limit (STEL). A limit value exposure should not occur and which is related to a 15-minute otherwise specified.

(5) μg/m3 = micrograms per cubic metre of air at 20 °C (760 mm mercury pressure).

(6) ppm = parts per million by volume in air (ml/m3).

(7) f/ml = fibres per millilitre.

(8) Substantial contribution to the total body burden via exposure.

(9) The substance may cause sensitisation of the skin respiratory tract.

(10) NCO refers to isocyanate functional groups of the compounds.

SCHEDULE II BINDING BIOLOGICAL LIMIT VALUES AND HEALTH SURVEILLANCE MEASURES

Legal Notice 164 of 2026.

SCHEDULE III

PROHIBITIONS production, manufacture or use at work of the chemical agents and activities chemical agents set out below are prohibited. The prohibition does not chemical agent is present in another chemical agent, or as a constituent provided that its individual concentration therein is less than the limit

Chemical Agents 1 2 ( ) CAS No ( ) Name of agent Concentration limit for exemption 91-59-8 2-naphthylamine and its salts 0,1% w/w 92-67-1 4-aminodiphenyl and its salts 0,1% w/w 92-87-5 Benzidine and its salts 0,1% w/w 92-93-3 4-nitrodiphenyl 0,1% w/w

EINECS: European Inventory of Existing Commercial Chemical Substances

Chemical Abstracts Service activities

SCHEDULE IV DANGEROUS SUBSTANCES

following chemical agents are to be considered dangerous within the meaning regulations:

explosive substances and preparations: solid, liquid, pasty or gelatinous and preparations which may also react exothermically without oxygen thereby quickly evolving gases, and which, under defined test detonate, quickly deflagrate or upon heating explode when partially oxidising substances and preparations: substances and preparations which a highly exothermic reaction in contact with other substances, flammable substances;

(c) extremely flammable substances and preparations: liquid preparations having an extremely low flash-point and a low boiling-point gaseous substances and preparations which are flammable in contact ambient temperature and pressure.

(d) highly flammable substances and preparations: - substances and preparations which may become hot and fire in contact with air at ambient temperature without any of energy, or - solid substances and preparations which may readily catch brief contact with a source of ignition and which continue be consumed after removal of the source of ignition, or - liquid substances and preparations having a very low flash-point, - substances and preparations which, in contact with water evolve extremely flammable gases in dangerous quantities;

(e) flammable substances and preparations: liquid substances and having a low flash-point;

(f) very toxic substances and preparations: substances and preparations in very low quantities cause death or acute or chronic damage to inhaled, swallowed or absorbed via the skin;

(g) toxic substances and preparations: substances and preparations quantities cause death or acute or chronic damage to health when inhaled, or absorbed via the skin;

(h) harmful substances and preparations: substances and preparations may cause death or acute or chronic damage to health when inhaled, absorbed via the skin;

(i) corrosive substances and preparations: substances and preparations may, on contact with living tissues, destroy them;

(j) irritant substances and preparations: non-corrosive substances preparations which, through immediate, prolonged or repeated contact or mucous membrane, may cause inflammation;

(k) sensitising substances and preparations: substances and preparations if they are inhaled or if they penetrate the skin, are capable of eliciting hypersensitisation such that on further exposure to the substance of characteristic adverse effects are produced;

(l) carcinogenic substances and preparations: substances or preparations if they are inhaled or ingested or if they penetrate the skin, may induce increase its incidence;

(m) mutagenic substances and preparations: substances and preparations if they are inhaled or ingested or if they penetrate the skin, may induce genetic defects or increase their incidence;

(n) substances and preparations which are toxic for reproduction: and preparations which, if they are inhaled or ingested or if they penetrate may produce, or increase the incidence of, non-heritable adverse progeny and/or an impairment of male or female reproductive functions SCHEDULE V Substituted by: L.N. 353 of 2007; L.N. 53 of 2012; L.N.57 of 2018; L.N. 356 of 2021. OCCUPATIONAL EXPOSURE LIMIT VALUES

No (2) Name of agent Limit values Notation (3) Eight hours (4) Short-term (5) mg/ ppm mg/ pp m3 (7) m3 m

(6) (6) (7) 54-11-5 Nicotine 0.5 - - - skin 55-63-0 Glycerol trinitrate 0.095 0.01 0.19 0.02 skin Carbon tetrachloride; 56-23-5 Tetrachloromethane 6.4 1 32 5 skin 60-29-7 Diethylether 308 100 616 200 -61-82-5 Amitrole 0.2 - - - -62-53-3 Aniline (15) 7.74 2 19.35 5 skin 64-18-6 Formic acid 9 5 - - -64-19-7 Acetic acid 25 10 50 20 -67-56-1 Methanol 260 200 - - skin 67-64-1 Acetone 1210 500 - - -67-66-3 Chloroform 10 2 - - skin N,N-68-12-2 Dimethylformamide 15 5 30 10 skin 71-55-6 1,1,1-Trichloroethane 555 100 1100 200 -74-87-3 Chloromethane 42 20 - - -Hydrogen cyanide 74-90-8 (as cyanide) 1 0.9 5 4.5 skin 75-00-3 Chloroethane 268 100 - - -75-04-7 Ethylamine 9.4 5 - - -75-05-8 Acetonitrile 70 40 - - skin Methylene chloride; 75-09-2 Dichloromethane 353 100 706 200 skin 200-843-6 75-15-0 Carbon disulphide 15 5 -200-863-5 75-34-3 1,1-Dichloroethane 412 100 -Vinylidene chloride; 200-864-0 75-35-4 1,1- Dichloroethylene 8 2 20 200-870-3 75-44-5 Phosgene 0.08 0.02 0.4 Chlorodifluoromethan 200-871-9 75-45-6 e 3600 1000 -200-875-0 75-50-3 Trimethylamine 4.9 2 12.5 201-083-8 78-10-4 Tetraethyl orthosilicate 44 5 -201-142-8 78-78-4 Isopentane 3000 1000 -201-159-0 78-93-3 Butanone 600 200 900 201-176-3 79-09-4 Propionic acid 31 10 62 Acrylic acid; Prop-2-8 201-177-9 79-10-7 enoic acid 29 10 59( ) 201-188-9 79-24-3 Nitroethane 62 20 312 Bisphenol A; 4,4’-Isopropylidenedipheno 9 201-245-8 80-05-7 l 2( ) - -201-297-1 80-62-6 Methyl methacrylate - 50 -201-865-9 88-89-1 Picric acid 0.1 - -202-049-5 91-20-3 Naphtalene 50 10 -202-422-2 95-47-6 o-Xylene 221 50 442 202-425-9 95-50-1 1,2-Dichlorobenzene 122 20 306 1,2,4-202-436-9 95-63-6 Trimethylbenzene 100 20 -202-500-6 96-33-3 Methyl acrylate 18 5 36 2-Phenyl-propane 15 202-704-5 98-82-8 (Cumene) ( ) 50 10 250 202-705-0 98-83-9 2-Phenylpropene 246 50 492 202-716-0 98-95-3 Nitrobenzene 1 0.2 -202-849-4 100-41-4 Ethylbenzene 442 100 884 202-981-2 101-84-8 Diphenyl ether 7 1 14 203-234-3 104-76-7 2-Ethylhexan-1-ol 5.4 1 -203-300-1 105-46-4 sec-Butylacetate 241 50 723 ε-Caprolactam (dust 203-313-2 105-60-2 and vapour) 10 - 40 203-388-1 106-35-4 Heptan-3-one 95 20 -203-396-5 106-42-3 p-Xylene 221 50 442 1,4-Dichlorobenzene; 203-400-5 106-46-7 p- Dichlorobenzene 12 2 60 203-403-1 106-49-0 4-aminotoluene 4.46 1 8.92 Acrolein; Acrylaldehyde; 203-453-4 107-02-8 Prop-2-enal 0.05 0.02 0.12 203-470-7 107-18-6 Allyl alcohol 4.8 2 12.1 203-473-3 107-21-1 Ethylene glycol 52 20 104 107-31-3 Methyl formate 125 50 250 100 skin 107-98-2 1-Methoxy-2-propanol 375 100 568 150 skin 108-05-4 Vinyl acetate 17.6 5 35.2 10 skin 108-10-1 4-Methylpentan-2-one 83 20 208 50 -108-38-3 m-Xylene 221 50 442 100 skin 108-46-3 Resorcinol 45 10 - - skin 2-Methoxy-1-108-65-6 methylethyl acetate 275 50 550 100 skin Mesitylene 108-67-8 (Trimethylbenzes) 100 20 - - -108-88-3 Toluene 192 50 384 100 skin 108-90-7 Monochlorobenzene 23 5 70 15 -108-94-1 Cyclohexanone 40.8 10 81.6 20 skin 108-95-2 Phenol 8 2 16 4 skin 109-66-0 Pentane 3000 1000 - - -109-86-4 2-Methoxyethanol - 1 - - skin 109-89-7 Diethylamine 15 5 30 10 -109-99-9 Tetrahydrofuran 150 50 300 100 skin 110-12-3 5-Methylhexan-2-one 95 20 - - -110-19-0 Isobutyl acetate 241 50 723 150 -110-43-0 Heptan-2-one 238 50 475 100 skin 2-Methoxyethyl 110-49-6 acetate - 1 - - skin 110-54-3 n-Hexane 72 20 - - -110-65-6 But-2-yne-1,4-diol 0.5 - - - -110-80-5 2-Ethoxyethanol 8 2 - - skin 110-82-7 Cyclohexane 700 200 - - -110-85-0 Piperazine 0.1 - 0.3 - -110-86-1 Pyridine 15 5 - - -110-91-8 Morpholine 36 10 72 20 -111-15-9 2-Ethoxyethyl acetate 11 2 - - skin 111-76-2 2-Butoxyethanol 98 20 246 50 skin 2-(2-Methoxyethoxy)ethan 111-77-3 ol 50.1 10 - - skin 112-07-2 2-Butoxyethyl acetate 133 20 333 50 skin 2-(2-112-34-5 Butoxyethoxy)ethanol 67.5 10 101.2 15 -115-10-6 Dimethylether 1920 1000 - - -1,2,4-120-82-1 Trichlorobenzene 15.1 2 37.8 5 skin 121-44-8 Triethylamine 8.4 2 12.6 3 skin 123-51-3 Isoamyl alcohol 18 5 37 10 -123-86-4 n-Butyl acetate 241 50 723 150 -123-91-1 1,4-Dioxane 73 20 - - -204-662-3 123-92-2 Isopentylacetate 270 50 540 204-696-9 124-38-9 Carbon dioxide 9000 5000 -204-697-4 124-40-3 Dimethylamine 3.8 2 9.4 204-825-9 127-18-4 Tetrachloroethylene 138 20 275 N,N-204-826-4 127-19-5 Dimethylacetamide 36 10 72 205-438-8 140-88-5 Ethyl acrylate 21 5 42 205-480-7 141-32-2 acrylate 11 2 53 n-Butyl 205-483-3 141-43-5 2-Aminoethanol 2.5 1 7.6 205-500-4 141-78-6 Ethyl acetate 734 200 1468 205-563-8 142-82-5 n-Heptane 2085 500 -Sodium cyanide (as 205-599-4 143-33-9 cyanide) 1 - 5 205-634-3 144-62-7 Oxalic acid 1 - -Potassium cyanide (as 205-792-3 151-50-8 cyanide) 1 - 5 206-992-3 420-04-2 Cyanamide 1 0.58 -Diacetyl; 207-069-8 431-03-8 Butanedione 0.07 0.02 0.36 207-343-7 463-82-1 Neopentane 3000 1000 -1,2,3-208-394-8 526-73-8 Trimethylbenzene 100 20 -5-Methylheptan-3-208-793-7 541-85-5 one 53 10 107 210-866-3 624-83-9 Methyl isocyanate - - -1-Methylbutyl 210-946-8 626-38-0 acetate 270 50 540 211-047-3 628-63-7 Pentyl acetate 270 50 540 211-128-3 630-08-0 Carbon monoxide 23 20 117 n-Methyl-2-212-828-1 872-50-4 pyrrolidone 40 10 80 10 10 215-137-3 1305-62-0 Calcium dihydroxide 1( ) - 4( ) 10 10 215-138-9 1305-78-8 Calcium oxide 1( ) - 4( ) Diphosphorus 215-236-1 1314-56-3 pentaoxide 1 - -Diphosphorus 215-242-4 1314-80-3 pentasulphide 1 - -

215-293-2 1319-77-3 Cresols (all isomers) 22 5 -Xylene, mixed 215-535-7 1330-20-7 isomers, pure 221 50 442 Tert-Butyl methyl 216-653-1 1634-04-4 ether 183.5 50 367 222-995-2 3689-24-5 Sulphotep 0.1 - -231-116-1 7440-06-4 Platinum (metallic) 1 - -231-131-3 7440-22-4 Silver, metallic 0.1 - -Silver (soluble compounds as Ag) 0.01 - - - -7446-09-5 Sulphur dioxide 1.3 0.5 2.7 1 -7580-67-8 Lithium hydride - - 0.02(9) - -7647-01-0 Hydrogen chloride 8 5 15 10 -7664-38-2 Orthophosphoric acid 1 - 2 - -7664-39-3 Hydrogen fluoride 1.5 1.8 2.5 3 -7664-41-7 Ammonia, anhydrous 14 20 36 50 -Sulphuric acid mist 7664-93-9 (11)(12) 0.05 - - - -7697-37-2 Nitric acid - - 2.6 1 -7726-95-6 Bromine 0.7 0.1 - - -7782-41-4 Fluorine 1.58 1 3.16 2 -7782-50-5 Chlorine - - 1.5 0.5 -7783-06-4 Hydrogen sulphide 7 5 14 10 -7783-07-5 Dihydrogen selenide 0.07 0.02 0.17 0.05 -7803-51-2 Phosphine 0.14 0.1 0.28 0.2 -Pyrethrum (purified of sensitising 8003-34-7 lactones) 1 - - - -Phosphoryl 10025-87-3 trichloride 0.064 0.01 0.12 0.02 -Phosphorus 10026-13-8 pentachloride 1 - - - -10035-10-6 Hydrogen bromide - - 6.7 2 -Nitrogen 13 10102-43-9 monoxide( ) 2.5 2 - - -10102-44-0 Nitrogen dioxide 0.96 0.5 1.91 1 -26628-22-8 Sodium azide 0.1 - 0.3 - skin (2-Methoxy-methylethoxy)-34590-94-8 propanol 308 50 - - skin Terphenyl, 61788-32-7 hydrogenated 19 2 48 5 -620-11-1 3-Pentylacetate 270 50 540 100 -625-16-1 Amylacetate, tert 270 50 540 100 -Fluorides, inorganic 2.5 - - - -Barium (soluble compounds as Ba) 0.5 - - - -Chromium Metal, Inorganic Chromium 2 - - - -

(II) Compounds and Inorganic Chromium

(III) Compounds (insoluble) Tin (inorganic compounds as Sn) 2 - -Mercuryanddivalent inorganic mercury compoundsincluding mercuric oxides and 0.02 mercuric chloride (measured 14 as mercury) ( ) Manganese and inorganicmanganese 0.2 (9) compounds (as 10 manganese) 0.05( ) (1 ) EC No: European Community (EC) number, the numerical identifier for substances within the European

(2) CAS No: Chemical Abstract Service Registry Number. 3 ( ) A skin notation assigned to the occupational exposure limit value indicates the possibility of significant through the skin.

(4) Measured or calculated in relation to a reference period of eight-hours as a time-weighted average. 5 ( ) Short-term exposurelimit(STEL).Alimit value above whichexposure should not occurand isrelated minute period, unless otherwise specified. 6 ( ) mg/m 3: milligrams per cubic metre of air at 20 °C and 101.3 KPa.

(7) ppm: parts per million by volume in air (ml/m3). 8 ( ) Short-term exposure limit value in relation to a reference period of 1 minute.

(9) Inhalable fraction. 10 ( )Respirable fraction. (11)When selecting an appropriate exposure monitoring method , account should be taken of potential limitations and interferences that may arise in the presence of other sulphur compounds. (12)The mist is defined as the thoracic fraction. 13 ( )Established in accordance with the Annex to Directive. (14)Duringexposuremonitoringformercuryanditsdivalentinorganiccompounds, accountshouldbetaken relevant biological monitoring techniques that complement the OELV. 15 ( )During exposure monitoring, account should be taken of relevant biological monitoring values as suggested the Scientific Committee on Occupational Exposure Limits for Chemical Agents (SCOEL).